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Beilstein J. Org. Chem. 2014, 10, 2139–2144, doi:10.3762/bjoc.10.221
Graphical Abstract
Scheme 1: Schematic representation of an imidazole–Ag(I)–imidazole base pair (top) and a thyminate–Hg(II)–thy...
Figure 1: Different views of a DNA duplex comprising three neighbouring imidazole–Ag(I)–imidazole base pairs....
Scheme 2: Schematic representation of silver(I)-mediated imidazole homo base pairs involving 2-methylimidazol...
Scheme 3: Synthesis of methylimidazole-based nucleosides and their corresponding phosphoramidites required fo...
Scheme 4: Oligonucleotide sequences under investigation (X = 2-methylimidazole 2a or 4-methylimidazole 2b).
Figure 2: Melting curves based on normalized UV absorbance at 260 nm of a) duplex I with X = 4-methylimidazol...
Figure 3: CD spectra of a) duplex I with X = 4-methylimidazole and b) duplex II with X = 2-methylimidazole in...